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Used Hydrogen Gas Generating Plant 18.5 MMSCFD. Designed by Fluor, built 1982, furnace designed by Foster Wheeler. The plant produces 18.5 MMSCFD of 96-mol percent hydrogen at 245 psig. Carbon dioxide is produced as a by-product at a rate of 23,350 lb/hr. The hydrogen plant also produced 22,000 lb/hr (net) 640 lb superheated steam for refinery use. The hydrogen plant is a steam/methane reformer with high and low temperature shift reactors. Treated refinery fuel gas and commercial natural gas are used as feed. There are two zinc oxide beds for removal of trace sulfur compounds. A hydrotreating catalyst converts sulfur compounds to hydrogen sulfide and zinc oxide removes the hydrogen sulfide. Feed gas is compressed to 385 psig, heated to 650F in the furnace. The feed gas is hydrotreated and zinc oxide c, and mixed with 640 psi superheated steam. The mixture is heated to 900 F and passed through 72 reformer catalyst tubes inside the furnace. Methane and other light hydrocarbons react with water to produce hydrogen and carbon monoxide. The carbon monoxide and water react to produce hydrogen and carbon dioxide in the high and low temperature shift reactors. The HTS reactor (850F outlet) increases the shift rate and the LTS reactor (450F outlet) promotes high equilibrium conversion. CO2 present in the LTS gas is removed by contact with activated potassium carbonate solution in a continuous recirculation Benfield design system. The conversion of trace carbon oxides is the final step in the purification process. The methanator contains a nickel-based catalyst to react carbon oxides with hydrogen, producing methane and water.
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Used Hydrogen Gas Generating Plant 18.5 MMSCFD. Designed by Fluor, built 1982, furnace designed by Foster Wheeler. The plant produces 18.5 MMSCFD of 96-mol percent hydrogen at 245 psig. Carbon dioxide is produced as a by-product at a rate of 23,350 lb/hr. The hydrogen plant also produced 22,000 lb/hr (net) 640 lb superheated steam for refinery use. The hydrogen plant is a steam/methane reformer with high and low temperature shift reactors. Treated refinery fuel gas and commercial natural gas are used as feed. There are two zinc oxide beds for removal of trace sulfur compounds. A hydrotreating catalyst converts sulfur compounds to hydrogen sulfide and zinc oxide removes the hydrogen sulfide. Feed gas is compressed to 385 psig, heated to 650F in the furnace. The feed gas is hydrotreated and zinc oxide c, and mixed with 640 psi superheated steam. The mixture is heated to 900 F and passed through 72 reformer catalyst tubes inside the furnace. Methane and other light hydrocarbons react with water to produce hydrogen and carbon monoxide. The carbon monoxide and water react to produce hydrogen and carbon dioxide in the high and low temperature shift reactors. The HTS reactor (850F outlet) increases the shift rate and the LTS reactor (450F outlet) promotes high equilibrium conversion. CO2 present in the LTS gas is removed by contact with activated potassium carbonate solution in a continuous recirculation Benfield design system. The conversion of trace carbon oxides is the final step in the purification process. The methanator contains a nickel-based catalyst to react carbon oxides with hydrogen, producing methane and water.
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